Synthesis, Characterization, Spectral Studies and Antimicrobial Study on Mixed Ligand Complexes of Chloro-arsenic(III) Derived from β-Ketiminates & Piperidine Dithiocarbamate Ligand Moity

Main Article Content

Deepak Kumar Sharma
Jyoti Sharma
Ramavtar Sharma

Abstract

A series of Chloro-arsenic(III) complexes with N, O donor β-ketiminate ligand (L1) and S, S donor piperidine dithiocarbamate ligand (L2) have been  synthesized by the reactions of AsCl3 with both ligands in equimolar ratio by stirring at room temperature in benzene solution. All these synthesized compounds have been characterized by Elemental Analysis, IR, (1H and 13C) NMR Spectral and ESI-Mass Studies. Both Ligands and their corresponding Chloro-arsenic (III) complexes have been screened for antimicrobial activity against the various bacterial (E. Coli, B. Subtalis and P. Aeruginosa) and fungal (T. Resei, P. Funiculosum and Fusarium) strains and results obtained .

Keywords:
Arsenic-trichloride, Heterocyclic dithiocarbamate, β-Ketiminate, (1H and 13C) NMR spectral studies, antimicrobial activity.

Article Details

How to Cite
Kumar Sharma, D., Sharma, J., & Sharma, R. (2019). Synthesis, Characterization, Spectral Studies and Antimicrobial Study on Mixed Ligand Complexes of Chloro-arsenic(III) Derived from β-Ketiminates & Piperidine Dithiocarbamate Ligand Moity. Asian Journal of Chemical Sciences, 6(4), 1-9. https://doi.org/10.9734/ajocs/2019/v6i419002
Section
Original Research Article

References

Barbier JP, Hugel RP, Kappenstein C, Inorg. Chim. Acta. 1983;77:117–118.

Caul BB, Pandeya KB. J. Inorg. Nucl. Chem. 1981;43:1942–1944.

Hogarth G. Prog. Inorg. Chem. 2005;53: 71–82.

Thorn GD, Ludwig RA, Bond AM, Martin . Coord. Chem. Rev. 1984;54:23–44.

Riekkola ML, Makitie O, Sundberg M, Kem. Kemi. 1979;6:525–529.

Khan S, Nami SA, Siddiqi KS, J. Organomet. Chem. 2008;693:1049–1057.

Deshpande UG, Shah JR. J. of Macromolecular Science: Part A. 1983; 20:355–363.

Cotton FA. Progress in Inorganic Chemistry. New York, USA, Wiley. 1966;7.

Chouhan HPS, Singh UP. Applied organomateliic chem. 2006;20:404-410.

Fahmi N, Kumari A, SinghRV. IJPSR. 2014;5:5260-5266.

Dawara L, Joshi SC, Singh RV. International Journal of Inorganic Chem. 2012;372141:1-9.

Sharma K, Singh RV, Fahmi N, Spectrochimica Acta Part A. 2011;78:80–87.

Kulkarni A, Avaji PG, Bagihalli GB, Patil SA, Badami PS. J. of Coord. Chem. 2009; 62:481–492.

D Kr. Sharma, Gupta R, Singh YP, Sharma J. J.of Coordination chem. 2014; 67:1478-1490.

Gupta R, Sharma J, Gupta MK, Singh YP, IJRTST. 2014;9:315-317.

Basu Baul TS. Applied Organometallic Chem. 2008;22:195–204.

Li M-X, Zhou J, Zhao H, Chen C-L, Wang J-P. J. of Coord. Chem. 2009;62:1423–1429.

Shanker D, Sharma RK, Sharma J, Rai AK, Singh YP. Heteroatom Chem. 2007;18:70–75.

Singh K, Singh DP, Singh Barwa M, Tyagi P, Mirza Y. J. of Enzyme Inhibition and Medicinal Chem. 2006;21:749–755.

Yadav S, Singh RV. Spectrochimica Acta Part A. 2011;78:298–306.

Akbar Ali M, Mirza AH, Voo CW, Tan AL, Bernhardt PV. Polyhedron. 2003;22:3433–3438.

Chouhan HPS, Abhilasha Bakhsi, Sumit bhatiya. Spectrochem Act A,Mol and Biomol. 2011;81:417-426.

Vrana J, Jambor R, Ruzicka A, Lycka A, Dostal L. J. Of Organometallic. Chem. 2013;723:10-14.

Agrawal R, Sharma J, Nandani D, Batra A, Singh YP. Journal of Coordination Chem. 2011;64:554-563.

Beveridge AD, Harris GS, Inglis F. J .Chem. Soc (A). 1966;520-528.

Marcotrigiano G, Pellaceni GC, Pretii C. J. Of. Inorganic and Nuclear Chem. 1974; 36:3709-3913.

Vogal AI. A text book of quantative inorganic analysis 5th edition; 1989.

Sharma DK, Sharma J, Singh YP. J. Coord. Chem. 2014;67:1413-1422.

Tweedy BG. Phytopathology. 1942;55: 910-916.