One Pot Synthesis of Cu(II) and Ni(II) Peroxo Complexes Containing Schiff Base: Physicochemical, Spectral and Antibacterial Investigations

Main Article Content

Md. Mahasin Ali
Md. Nur Amin Bitu
Md. Saddam Hossain
Md. Faruk Hossen
Md. Ali Asraf
Md. Akhter Farooque
Md. Kudrat-E- Zahan

Abstract

Two new peroxo complexes of Cu(II) and Ni(II) ion containing Schiff base (SB) were synthesized and characterized by TLC, Elemental analyses, conductivity, magnetic moment measurements, UV-Vis. and IR and ESI-MS spectral studies. The Schiff base ligand derived from cinnamaldehyde and o-aminophenol participated in complexation through a single pot reaction. IR spectra showed that the Schiff base ligand coordinated to the metal ion through nitrogen of azomethine group and oxygen of hydroxyl group & peroxo group (O-O). Magnetic moment value coupled with electronic spectral data suggested a square planar geometry for both the complexes. The molar conductance values indicated the non-electrolytic nature of the complexes. Antibacterial activity of the complexes was tested against four pathogenic bacteria, two Gram-positive Staphylococcus aureus & Bacillus cereus and two Gram-negative Escherichia coli & Shigella dysenteriae with Kanamycin (K-30) standard. The result shows that Cu(II) complex exhibited more potential antibacterial activity than the Ni(II) complex against all the tested organisms.

Keywords:
Peroxo complexes, schiff base, cinnamaldehyde, o-aminophenol, antibacterial activity

Article Details

How to Cite
Ali, M. M., Bitu, M. N. A., Hossain, M. S., Hossen, M. F., Asraf, M. A., Farooque, M. A., & Zahan, M. K.-E.-. (2020). One Pot Synthesis of Cu(II) and Ni(II) Peroxo Complexes Containing Schiff Base: Physicochemical, Spectral and Antibacterial Investigations. Asian Journal of Chemical Sciences, 8(1), 15-21. https://doi.org/10.9734/ajocs/2020/v8i119032
Section
Original Research Article

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