Synthesis and Characterization of Short Alkyd Resin Based on Sesame Seed Oil as Binder for Coating Industry
Kalu M. Kalu
*
Department of Chemistry, Gombe state University, P.M.B 127, Tudun Wada, Gombe, Gombe State, Nigeria.
Adam Aliyu
Department of Chemistry, College of Education, Zing, Taraba State, Nigeria.
Emmanuel K. Chinedu
Department of Chemistry, Modibbo Adama University, Yola, Adamawa State, Nigeria.
Nnaneme F. O.
Department of Chemistry, Nnamdi Azikiwe University, Awka, Nigeria.
*Author to whom correspondence should be addressed.
Abstract
Alkyd resin of 40 % oil length was synthesized from the polyesterification reaction of glycerol, pthalic anhydride and sesame seed oil. Physicochemical properties such as iodine value, saponification value, density, moisture absorption, acid value and viscosity were determined to be 70.2 gI2/100g, 227.5 mgKOH/100g, 0.953 g/cm3, 0.22%, 9.23 KOH/g and 123.22 m.Pa.s respectively for the sesamum indicum seed oil modified alkyd resin (SISOMAR). Differential scanning calorimetry and thermogravimetric analysis were employed for the characterization of the alkyd resin. The glass transition (Tg) value of the 40% alkyd resin was 34.99 °C, initial degradation temperature (Ti), final degradation temperature (Tf) were 300 °C and > 500 °C respectively. It was identified that the SISOMAR could meet with temperature resistance and mechanical requirements to serve as a potential binder for the coating industry.
Keywords: Alkyd resin, sesame, alcoholysis, polyesterification
How to Cite
Downloads
References
Zech-Matterne V, Tengberg M, Van Andringa W. Sesamum indicum L. (sesame) in 2nd century bc Pompeii, southwest Italy, and a review of early sesame finds in Asia and Europe,” Veg Hist Archaeobot. 2015;24(6):673–681. DOI: 10.1007/s00334-015-0521-3.
Bedigian D. Characterization of sesame (Sesamum indicum L.) germplasm: A critique. Genet Resour Crop Evol. 2010;57 (5):641–647. DOI: 10.1007/s10722-010-9552-x.
Majdalawieh AF, Massri M, Nasrallah GK. A comprehensive review on the anti-cancer properties and mechanisms of action of sesamin, a lignan in sesame seeds (Sesamum indicum). European Journal of Pharmacology. Elsevier B.V. 2017;815:512–521. DOI: 10.1016/j.ejphar.2017.10.020.
Ali Mutar M, Wahab Hassan A, Ail Mutar M, Mohammed Abdul Hassan N. Chemical - IJCPT-Synthesis and Characterization of New alkyd resins _Short, medium and long _ based on sunflower oil and linoleic acid as binder for Paints. 2017. [Online]. Available: www.tjprc.org
Kalu KM et al. Extraction, synthesis and characterization of an alkyd resin from sesamum indicum seed oil. Oalib. vol. 2023;10(07):1–18. DOI: 10.4236/oalib.1110447.
Kim YH et al. Sesamum indicum L. oil and sesamin induce auditory-protective effects through changes in hearing loss-related gene expression. J Med Food. 2020;23 (5):491–498. DOI: 10.1089/jmf.2019.4542.
Osemeahon SA, Barminas. Development of amino resin for emulsion paint formulation: Reactive blending of methylol urea with soybean oil. Afr J Biotechnol. 2007;6(6):803–809. [Online]. Available:http://www.academicjournals.org/AJB
Sanyaolu NO, Awosanya A, Sonde OI, Kareem FA, Yussuf ST, Akinwunmi F, Ibikunle AA. Comparative evaluation of the alkyd resins of the composite oils of soybean (Ricinus Communis) and castor (Glycine Max) Seed Oils with Castor Seed Oil for Alkyd Paint Formulation. Journal of Chemical Society of Nigeria. 2019;44(5): 914 -921.
Desai SD, Patel JV, Sinha VK. Polyurethane adhesive system from biomaterial-based polyol for bonding wood. Int J Adhes Adhes. 2003;23(5):393–399. DOI: 10.1016/S0143-7496(03)00070-8.
Warra A. Sesame (Sesamum indicum L.) Seed oil methods of extraction and its prospects in cosmetic industry: A review. Bayero Journal of Pure and Applied Sciences. 2012;4(2). DOI: 10.4314/bajopas.v4i2.33.
Aloo Ikyenge B et al. Comparative analysis of soybean seed oil modified alkyd resin and epoxidized soybean seed oil modified alkyd resin and epoxidized soybean seed oil modified alkyd resin. International Journal of Modern Organic Chemistry. 2012;2:66–71, 2012, [Online]. Available:https://www.researchgate.net/publication/236119739
Kangas SL JFN. Binders of higher-solids coatings, part 1: Synthesis of model alkyds resins. Journal of Coating Technology. 2000;59:89–97.
Singh S. Preparation and analysis of alkyd resin from deodourizer distillate; 2009.
Gidigbi JA, Osemeahon SA, Ngoshe M, Babanyaya A, Coating Industry; 2019. [Online]. Available: www.ijriar.com
Kouba M, Mourot J. A review of nutritional effects on fat composition of animal products with special emphasis on n-3 polyunsaturated fatty acids, Biochimie. Elsevier B. V. 2011;93(1):13–17. DOI: 10.1016/j.biochi.2010.02.027.
Bobalek EG. Synthesis and properties of some alkyds of more complex carboxyl functionality; 1964.
Fasina AK. Chemistry and industry. In 14th Ann. National Conf. Chem. Soc. Nig. Petroleum Training Institute, Warri, Nigeiria; 1989.
Yebra DM, Kiil S, Dam-Johansen K. Antifouling technology: Pat, present and future steps towards efficient and environmentally friendly antifouling coatings. Progress Organic Coatings. 2004;(4):15-25.
Omnexus. Glass transition temperature (Tg) of plastics- Definition and values: Glass Transition Temperature (Tg) of Plastics - Definition and Values (specialchem.com).