Electrochemically Generated Aluminum-Species for Remediation of Waste Water Containing 2, 4-Dichlorophenol

Hasina Akhter Simol *

Centre for Advanced Research in Sciences, University of Dhaka, Bangladesh.

Rumana Akther Jahan

Centre for Advanced Research in Sciences, University of Dhaka, Bangladesh.

*Author to whom correspondence should be addressed.


Abstract

An effective treatment process for 2,4-dichlorophenol (2,4-DCP) in wastewater is highly essential, since it may cause great threat to our environment. In such context, a low-cost potential and environment-friendly technique has been demonstrated for the removal of a toxic compound 2,4-DCP from aqueous media. The electrochemically generated aluminum sorbent was used to remove 2,4-DCP from waste water by in-situ electrocoagulation and by adsorption. The experimental findings were analyzed based on the percent removal of 2,4-DCP with time. DCP-containing wastewater was electrocoagulated in a two-electrode monopolar electrocoagulation cell with aluminum as the sacrificial anode and 0.05 M NaCl as the internal electrolyte, with the electrolyte concentration kept constant throughout the experiment. Starting concentration and pH were found to have a significant impact on the electrocoagulation process for removing 2,4-DCP from wastewater.

Keywords: Aluminum sorbent, 2,4-Dichlorophenol (2,4-DCP), electrocoagulation, adsorption, sacrificial anode


How to Cite

Simol , H. A., & Jahan , R. A. (2023). Electrochemically Generated Aluminum-Species for Remediation of Waste Water Containing 2, 4-Dichlorophenol. Asian Journal of Chemical Sciences, 13(6), 193–205. https://doi.org/10.9734/ajocs/2023/v13i6274

Downloads

Download data is not yet available.

References

Shen YH. Removal of phenol from water by adsorption-flocculation using organobentonite. Water Res; 2002. DOI: 10.1016/S0043-1354(01)00324-4

Yapar S. Hydrotalcite as a potential sorbent for the removal of 2, 4-dichlorophenol. Turkish J Eng Environ Sci. 2004;28(1):41-48.

Mortland MM, Shaobai S, Boyd SA. Clay-organic complexes as adsorbents for phenol and chlorophenols. Clays Clay Miner; 1986. DOI: 10.1346/ccmn.1986.0340512

Campanella L, Beone T, Sammartino MP, Tomassetti M. Determination of phenol in wastes and water using an enzyme sensor. Analyst; 1993. DOI: 10.1039/AN9931800979

Contreras Iglesias S. Degradation and biodegradability enhancement of nitrobenzene and 2, 4-dichlorophenol by means of Advanced Oxidation Processes based on ozone. Universitat de Barcelona; 2003.

USEPA. Chemical advisory and notice of potential risk: Skin exposure to molten 2,4-Dichlorophenol Can Cause Rapid Death; 2000.

Kintz P, Tracqui A, Mangin P. Accidental death caused by the absorption of 2,4-dichlorophenol through the skin. Arch Toxicol; 1992. DOI: 10.1007/BF02307178

Hasina A Simol, Yousuf M, Mollah A, Mottalib MA. Electrogeneration of Al-oxyhydroxide and its characterization. J Bangladesh Acad Sci. 2007;31(1):143-149.

Mishra D, Anand S, Panda RK, Das RP. Hydrothermal preparation and characterization of boehmites. Mater Lett; 2000. DOI: 10.1016/S0167-577X(99)00156-1

Sato T, Yamashita T, Ozawa F. The Preparation of Bayerite from sodium aluminate solutions with carbon dioxide. ZAAC ‐ J Inorg Gen Chem; 1969. DOI: 10.1002/zaac.19693700312

Li G, Smith JL, Inomata H, Arai K. Synthesis and thermal decomposition of nitrate-free boehmite nanocrystals by supercritical hydrothermal conditions. Mater Lett; 2002.DOI: 10.1016/S0167-577X(01)00472-4

Tsyganenko AA, Filimonov VN. Infrared spectra of surface hydroxyl groups and crystalline structure of oxides. Spectrosc Lett; 1972. DOI: 10.1080/00387017208065418

Yousuf M, Mollah A, Cocke DL, Parga JR. An Infrared Spectroscopic Examination of Cement-Based Solidification/Stabilization Systems - Portland Types V and IP with Zinc. J Environ Sci Heal Part A Environ Sci Eng Toxicol; 1992. DOI: 10.1080/10934529209375809

Pavia DL, Lampman GM, Kriz GS. Introduction to Spectroscopy third edition. Thomson Learn Inc; 2001.

Cao W, Zeng C, Guo X, Liu Q, Zhang X, Mameda N. Enhanced electrochemical degradation of 2,4-dichlorophenol with the assist of hydrochar. Chemosphere. 2020;(260):127643.

DOI: 10.1016/j.chemosphere.2020.127643

Xiang L, Zhou M, Pan Y, Liting X. Pre-magnetized Fe0/persulfate for notably enhanced degradation and dechlorination of 2,4-dichlorophenol. Chemical Engineering Journal. 2017;(307):1092-1104. DOI: 10.1016/j.cej.2016.08.140

Chengyang W, Zhou L, Yun Z, Chen Z, Xia S, Bruce ER. Dechlorination of 2,4-dichlorophenol in a hydrogen-based membrane palladium-film reactor: Performance, mechanisms, and model development. Water Research. 2021;(188):116465. DOI: 10.1016/j.watres.2020.116465

Yongsong M, Yuxing G, Da J, Xuhui M, Dihua W. Degradation of 2,4-DCP using persulfate and iron/E-carbon micro-electrolysis coupling system. Journal of Hazardous Materials. 2021;(413): 125381. DOI: 10.1016/j.jhazmat.2021.125381

Xia R, Hong L, Junwen W, Zhao D, Xianyuan F. A new insight into the main mechanism of 2,4-dichlorophenol dechlorination by Fe/Ni nanoparticles. Science of The Total Environment. 2019;(697):133996.

DOI: 10.1016/j.scitotenv.2019.133996

Zhou J, Zimo L, Wang Z, Chuchen Z, Cheng L, Shams A B, Xinhua X. Electrocatalytic dechlorination of 2,4-DCBA using CTAB functionalized Pd/GAC movable granular catalyst: Role of adsorption in catalysis. Chemical Engineering Journal. 2021;(414): 128758.DOI: 10.1016/j.cej.2021.128758

Zhiqiao H, Tong W, Sulin N, Xincheng Y, Chengetai P M, Xinwen H, Shihan Z, Shuang S. Electrochemically reductive dechlorination of 3,6-dichloropicolinic acid on a palladium/nitrogen-doped carbon/nickel foam electrode. Electrochimica Acta. 2018;(292):685-696. DOI: 10.1016/j.electacta.2018.09.188

Krzysztof K, Mateusz S, Andrzej Ś. Adsorption of 2,4-dichlorophenol and 2,4-dichlorophenoxyacetic acid from aqueous solutions on carbonaceous materials obtained by combustion synthesis. Journal of the Taiwan Institute of Chemical Engineers. 2016;(63):371-378.DOI: 10.1016/j.jtice.2016.03.036

Garba ZN, Rahim AA. Evaluation of optimal activated carbon from an agricultural waste for the removal of para-chlorophenol and 2,4-dichlorophenol. Process Safety and Environmental Protection. 2016(102):54-63. DOI: 10.1016/j.psep.2016.02.006

Zhanping C, Minghui Z, Jingli Z, Hongwei Z. Impact of continuous and intermittent supply of electric assistance on high-strength 2,4-dichlorophenol (2,4-DCP) degradation in electro-microbial system. Bioresource Technology. 2016;(212):138-143. DOI: 10.1016/j.biortech.2016.03.165